0

Platinum-catalyzed Addition of Dimethylsilylene to Beta-Methyl Alpha,beta-Unsaturated Ketones: Gamma-Silylation Forming 1-oxa-2-silacyclohex-5-enes

Kazuhiro Okamoto, Tamio Hayashi

Org Lett. 2007 Nov 22;9(24):5067-9.

PMID: 17973489

Abstract:

The reaction of beta-methyl alpha,beta-unsaturated ketones with pentamethyldisilane in the presence of a platinum catalyst brought about silylation on the beta-methyl group giving high yields of oxasilacyclohexenes.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP812157 Pentamethyldisilane Pentamethyldisilane 812-15-7 Price
qrcode